While detectors for H2 leaks are available, they require high temperatures to operate (such as the metal-oxide semiconductor-based gas sensors) making them expensive, short-lived, and dangerous to use for detection of an explosive or flammable gas. They also suffer from low sensitivity due to a lack of enough active sites for gas detection (such as zinc oxide [ZnO] “nanosheets”). Scientists, therefore, have been busy developing sensors that can overcome these limitations.
In a new study published in Sensors and Actuators: B. Chemical, a team of scientists from Incheon National University, Korea, have come up with a novel room temperature H2 sensor design that makes use of nanometer-thin “2D” sheets of zinc oxide filled with nanometer-size holes and is aptly named “Holey 2D nanosheets.” “Ordinary ZnO nanosheets have low sensitivity due to self-restacking that blocks the active sites for gas detection. Holey 2D nanosheets get around this problem with the holes opening up blocked active surfaces,” explains Dr. Manjeet Kumar, who led the study.
The scientists thermally “treated” ZnO nanosheets at three different temperatures (400°C, 600°C, & 800°C) to tune their hole density, fabricated H2 sensor devices from these samples, and recorded their response to different levels of H2 and other gases at 100 ppm (parts per million) gas concentration at room temperature. The team also investigated the validity of the “metallization theory,” which suggests that the underlying sensing mechanism is due to a semiconductor-to-metal transition, in which ZnO gets “reduced” to Zn metal under exposure to H2 gas.
They found that the ZnO nanosheet treated at 400°C (ZnO@400), with the maximum number of holes, showed the highest response towards 100 ppm of H2, along with the fastest response time of ~9 s. Furthermore, ZnO@400 also displayed high repeatability and stability of approximately 97-99% after 45 days. Finally, they found the experimental evidence to be in support of the metallization theory.
These results strongly suggest that 2D holey ZnO nanosheets possess remarkable physical/chemical properties that can potentially revolutionize gas sensing performance in the future. Dr. Kumar surmises, “Room temperature H2 sensors will play a key role in future technology, especially with the emergence of Internet of Things. Our holey 2D ZnO-based sensors will enable implementation of innovative H2 detection devices that can detect gas leakage at an early stage and can be integrated with smartphones and smartwatches,”
With a vision of a bright H2-powered future ahead of us, this technology goes a long way in ensuring a “safe” path to materializing this vision!
This content was originally published here.